Tag Archives: lithium hydroxide monohydrate

Metso’s sulphate-free alkaline pressure leach process wins Planet Positive accolade

Metso is expanding its sustainable offering for the lithium market, having validated its proprietary, sulphate-free alkaline pressure leach process as a Planet Positive technology for the production of battery-grade lithium.

Metso’s hydrometallurgical alkaline leach process is a simple and safe way to refine spodumene concentrate to battery-grade end products like lithium hydroxide monohydrate and lithium carbonate, the company says. The innovative refining process produces high-purity lithium salts and hydrates, which are needed for the cathodes of lithium-ion batteries used in electric vehicles.

In the process, lithium is extracted with high yield. Inert and neutral mineral residue is minimised and ready to be reused or disposed of, thus minimising pollution to air, water and soil. No additional impurity removal or precipitation stages are needed. In recent studies, the alkaline leach process has also shown reduced environmental impact compared with other technologies, Metso says. Based on the Life Cycle Impact Assessment, the process can provide an up to 40-60% reduction in water consumption, as well a reduction in the acidification and eutrophication impact. The compact process also minimises plant footprint and embedded carbon, according to Metso.

Metso has been developing sustainable alkaline leaching technologies for hard-rock lithium sources for 20 years already. Today the offering includes proprietary technologies for refining lithium from spodumene mineral concentrates. Intensive R&D and piloting is also ongoing in the processing of other lithium-bearing pegmatite hard rocks such as petalite, zinnwaldite (with Zinnwald Lithium plc) and lepidolite. Metso says it also has proven processes also for the extraction of lithium from brines.

Alongside this, Metso is providing its Planet Positive sustainable soda pressure leaching technology for Keliber’s lithium hydroxide refinery, which will be built in Kokkola, Finland.

Marika Tiihonen, Technology Manager for Lithium at Metso, said: “The urgent need to implement solutions and technologies limiting global warming is driving the development of lithium-ion batteries that are used, for example, in electric vehicles and renewable energy storage ecosystems. This, and the regionalisation of critical minerals sourcing, has resulted in a surge in lithium projects. Currently, Metso is supporting several battery minerals projects that are in study, piloting, engineering or delivery phases.”

Tiihonen added: “As a strong and reliable partner for the development of lithium hydroxide and other battery minerals projects, Metso can deliver the whole production process – from mine to battery materials, and recycling of black mass – complemented with world-class service support.”

HALMEK LITHIUM to work with Metso Outotec on lithium hydroxide plant

HALMEK LITHIUM has selected Metso Outotec’s patented lithium hydroxide process for production of battery-grade lithium hydroxide at its greenfield plant in the Tula region in Russia.

The order value, which is not disclosed, has been booked in the company’s Metals June quarter orders received.

Metso Outotec’s scope of delivery consists of the engineering and key equipment supply for the lithium hydroxide process, the basis of which will be the Metso Outotec OKTOP® autoclave plant. The environmentally sound production process is one of Metso Outotec’s more than 100 Planet Positive products, the company said.

Pavel Galchenko, VP, Halmek Lithium, said: “One of the most important tasks in the project was the selection of technology. Instead of the more traditional sulphuric acid processing to produce lithium hydroxide, we decided to choose the Metso Outotec lithium hydroxide process as it is the most promising and environmentally-sound process at the moment.

“The pilot tests conducted at the Metso Outotec Research Center in Pori, Finland, provided excellent results.”

Mikko Rantaharju, Vice President, Hydrometallurgy business line at Metso Outotec, said: “Metso Outotec has developed lithium hard rock-related technologies for some 20 years now. It started with the battery-grade lithium carbonate process and, when the market changed to favour lithium hydroxide, the process flowsheet was converted to directly produce battery-grade lithium hydroxide monohydrate from spodumene.

“Both of the processes are patented and will be significant assets in our battery chemicals business, meeting the need to produce high-end lithium-ion battery chemistries for the growing market.”

HALMEK LITHIUM’s new hydrometallurgical plant, which will complement its existing lithium hydroxide plant, is currently under construction. As raw material, the new plant will use spodumene concentrate; it will feature a capacity of 20,000 t/y of battery-grade lithium hydroxide monohydrate, which is used in the production of batteries for electric vehicles. The first production line is planned to start up in 2023, and the second production line with a capacity of 20,000 t/y is expected to start production in 2026.

E3 Metals receives provincial funding for Direct Lithium Extraction pilot

Canada-based E3 Metals says it has received a government grant totalling C$1.8 million ($1.4 million) from Alberta Innovates that will assist it in funding a pilot plant to test out its proprietary Direct Lithium Extraction (DLE) technology.

DLE technology, the company says, seamlessly connects conventional oil field and lithium processing, with the potential to unlock Alberta’s previously untapped lithium resources.

This direct brine process produces a concentrate feedstock that could be turned into lithium hydroxide using conventional production equipment, according to the company, with the benefit of DLE being that it can achieve at least 20 times to almost 100 times concentration of lithium (up to 5,300 mg/L) with a reduction of over 99% of all impurities and an extraction time of hours. This is achieved with average lithium recoveries of over 90%, the company says.

“E3 Metals’ goal is to commercialise its global-scale lithium resource and deliver zero carbon emissions, battery grade lithium products to the growing electric vehicle supply chain,” it said.

The funding provided by Alberta Innovates is to support the demonstration E3 Metals’ DLE technology by progressively scaling it up from the lab prototype to a field pilot. The first step will be a prototype operating within E3 Metals’ Calgary lab, and then a field pilot operating continuously on a site within E3 Metals’ resource area in Alberta.

“By demonstrating the process at a pilot scale over numerous months, the company plans to significantly de-risk its Alberta lithium project prior to scaling up to the anticipated commercial scale of 20,000 t/y lithium hydroxide monohydrate,” it said.

Alberta Innovates is a provincially funded corporation with a mandate to deliver 21st century solutions for the most compelling challenges facing Albertans, E3 Metals says. It does this by building on the province’s research and technology development strengths in the core sectors of health, environment, energy, and food and fibre, and platforms such as clean technology, digital technology for business transformation, data-enabled innovation, and innovative production and distribution.

E3 Metals has 7 Mt of lithium carbonate equivalent inferred mineral resources in Alberta within the Leduc Reservoir. Some 1.9 Mt of this is confined within its Clearwater lithium project.